The effects of calcium and potassium on CO₂ gasification of birch wood in a fluidized bed
Kramb, Jason; Gómez-Barea, Alberto; DeMartini, Nikolai; Romar, Henrik; Rama K.C. Doddapaneni, Tharaka; Konttinen, Jukka (2017-02-11)
Jason Kramb, Alberto Gómez-Barea, Nikolai DeMartini, Henrik Romar, Tharaka Rama K.C. Doddapaneni, Jukka Konttinen, The effects of calcium and potassium on CO2 gasification of birch wood in a fluidized bed, Fuel, Volume 196, 15 May 2017, Pages 398-407, ISSN 0016-2361, http://dx.doi.org/10.1016/j.fuel.2017.01.101. (http://www.sciencedirect.com/science/article/pii/S0016236117301199)
© 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
https://creativecommons.org/licenses/by-nc-nd/4.0/
https://urn.fi/URN:NBN:fi-fe201703152209
Tiivistelmä
Abstract
Birch wood was leached of its naturally occurring ash forming elements and doped with three concentrations of calcium or potassium before being gasified in a laboratory bubbling fluidized bed reactor. The wood samples were pelletized and inserted into a fluidized bed reactor where they were first pyrolyzed with N₂ and then gasified with CO₂. In addition to tracking the gas concentration of the exit gas, char samples were taken from the fluidized bed and analyzed to study the char properties. The presence of potassium in the biomass was found to have a significant influence on the structure of the resulting char, however potassium did not have an observable catalytic effect on the overall gasification reaction rate with CO₂ due to the formation of a unreactive coke layer on the char surface. In contrast, calcium did increase the char conversion rate and is likely the primary active catalyst in gasification of birch wood with CO₂.
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