Meng, Wen; Zhang, Lahong; Li, Feng; Li, Feng; Li, Taohai; Cao, Wei (2017) One-pot hydrothermal synthesis of ZnC₄O₄ concave microspheres with superhydrophobic and superoleophilic properties. CrystEngComm, 2017, 19, 528-536. DOI: 10.1039/C6CE02144A
One-pot hydrothermal synthesis of ZnC₄O₄ concave microspheres with superhydrophobic and superoleophilic properties
|Author:||Meng, Wen1; Zhang, Lahong1; Li, Feng1;|
1College of Chemistry, Key Lab of Environment Friendly Chemistry and Application in Ministry of Education, Xiangtan University, Xiangtan, China
2Nano and Molecular Systems Research Unit, Faculty of Science, University of Oulu, P. O. Box 3000, FIN-90014, Finland
|Online Access:||PDF Full Text (PDF, 3.1 MB)|
|Persistent link:|| http://urn.fi/urn:nbn:fi-fe201703245829
Royal Society of Chemistry,
|Publish Date:|| 2017-03-24
In this study, we report a facile solution route to prepare superhydrophobic and superoleophilic ZnC₄O₄ concave microspheres. The surface morphologies and chemical compositions were determined through scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The wettability of the as-synthesized ZnC₄O₄ coordination compound surface was studied by measuring the contact angle (CA). A static CA for water over 160° was observed, which was closely related to both the structure and chemical modification of ZnC₄O₄, and a 0° static CA for octane was observed, which showed that the as-prepared ZnC₄O₄ surface had superoleophilic properties. Furthermore, the as-prepared ZnC₄O₄ surface showed superhydrophobicity for some corrosive liquids, such as acidic and basic aqueous solutions.
|Pages:||528 - 536|
|Type of Publication:||
A1 Journal article – refereed
|Field of Science:||
116 Chemical sciences
114 Physical sciences
The authors acknowledge with thanks the financial support of the Provincial Natural Science Foundation of Hunan, China (2015JJ2138), the National Natural Science Foundation of China (21601149), and the Strategic Grant from University of Oulu, Finland, and the European Union Regional Development Foundation.
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.