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Probing RbBr solvation in freestanding sub-2nm water clusters |
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| Author: | Hautala, Lauri1; Jänkälä, Kari1; Mikkelä, Mikko-Heikki2; |
| Organizations: |
1Nano and Molecular Systems Research Unit, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland 2MAX IV Laboratory, Lund University, Box 118, 22100 Lund, Sweden |
| Format: | article |
| Version: | accepted version |
| Access: | open |
| Online Access: | PDF Full Text (PDF, 2.5 MB) |
| Persistent link: | http://urn.fi/urn:nbn:fi-fe201803296278 |
| Language: | English |
| Published: |
Royal Society of Chemistry,
2017
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| Publish Date: | 2018-09-04 |
| Description: |
AbstractConcentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg−1. For comparison, spectra from anhydrous RbBr clusters are also presented. see all
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| Series: |
PCCP. Physical chemistry chemical physics |
| ISSN: | 1463-9076 |
| ISSN-E: | 1463-9084 |
| ISSN-L: | 1463-9076 |
| Volume: | 19 |
| Issue: | 36 |
| Pages: | 25158 - 25167 |
| DOI: | 10.1039/C7CP04398H |
| OADOI: | https://oadoi.org/10.1039/C7CP04398H |
| Type of Publication: |
A1 Journal article – refereed |
| Field of Science: |
114 Physical sciences 116 Chemical sciences |
| Subjects: | |
| Funding: |
The experiments were performed at MAX-lab (Sweden) at the I411 beamline (proposal number 20130121). EXACTUS doctoral program (University of Oulu) and Jenny and Antti Wihuri foundation are gratefully acknowledged by L. Hautala for their support. The authors would like to acknowledge the financial support from the Academy of Finland. This research has received funding from the European Community’s Seventh Framework Programme (FP7/2007-2013) CALIPSO (grant agreement no. 312284). |
| EU Grant Number: |
(717022) SURFACE - The unexplored world of aerosol surfaces and their impacts. |
| Copyright information: |
© The Owner Societies 2017. Published in this repository with the kind permission of the publisher. |