Comparison of the properties of activated carbons produced in one-stage and two-stage processes
|Author:||Bergna, Davide1,2; Varila, Toni1,2; Romar, Henrik1;|
1Research Unit of Sustainable Chemistry, University of Oulu, P.O. Box 3000, FI-90014 Oulu, Finland
2Unit of Applied Chemistry, University of Jyvaskyla, Kokkola University Consortium Chydenius, Talonpojankatu 2B, FI-67100 Kokkola, Finland
|Online Access:||PDF Full Text (PDF, 0.6 MB)|
|Persistent link:|| http://urn.fi/urn:nbn:fi-fe2018081333615
Multidisciplinary Digital Publishing Institute,
|Publish Date:|| 2018-08-13
Activated carbons (ACs) can be produced from biomass in a thermal process either in a direct carbonization-activation process or by ﬁrst carbonizing the biomass and later activating the bio-chars into activated carbons. The properties of the ACs are dependent on the type of process used for production. In this study, the properties of activated carbons produced in one-stage and two-stage processes are considered. Activated carbons were produced by physical activation of two types of starting materials: bio chars produced from spruce and birch chips in a commercial carbonization plant and from the corresponding raw chips. The activated carbons produced were characterized regarding speciﬁc surfaces, pore volumes, and pore size distributions. The un-activated bio chars had varying surface areas, 190 and 140 m² g⁻¹ for birch and spruce, respectively, and pore volumes of 0.092 and 0.067 cm³ g⁻¹, respectively. On the other hand, 530–617 and 647–679 m² g⁻¹ for activated bio chars from birch and spruce, respectively, and pore volumes 0.366–0.509 and 0.545–0.555 cm³ g⁻¹, respectively, were obtained. According to the results obtained, two slightly different types of activated carbons are produced depending on whether a one-stage or a two-stage carbonization and activation process is used. The ACs produced in the one-stage process had higher speciﬁc surface areas (SSA), according to the BET-model (Brunauer–Emmett–Teller), compared to the ones produced in a two-stage process (761–940 m² g⁻¹ vs. 540–650 m² g⁻¹, respectively). In addition, total pore volumes were higher in ACs from the one-stage process, but development of micro-pores was greater compared to those of the two-stage process. This indicates that the process can have an inﬂuence on the ACs’ porosity. There was no signiﬁcant difference in total carbon content in general between the one-stage and two-stage processes for spruce and birch samples, but some differences were seen between the starting materials. Especially in the one-stage procedure with 2 and 4 h steam activation, there was nearly a 10% difference in carbon content between the spruce and birch samples.
C. Journal of carbon research
|Type of Publication:||
A1 Journal article – refereed
|Field of Science:||
116 Chemical sciences
The study was supported by and performed within the projects Renepro (20200224) funded by Interreg Nord (H.R.) and BothniaBioraff (T.V.). Economical support was received from the Central Ostrobothnia Cultural Foundation (D.B.).
© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).