University of Oulu

Chubb, K., Naumenko, O., Keely, S., Bartolotto, S., Macdonald, S., Mukhtar, M., Grachov, A., White, J., Coleman, E., Liu, A., Fazliev, A., Polovtseva, E., Horneman, V., Campargue, A., Furtenbacher, T., Császár, A., Yurchenko, S., Tennyson, J. (2018) Marvel analysis of the measured high-resolution rovibrational spectra of H232S. Journal of Quantitative Spectroscopy and Radiative Transfer, 218, 178-186. doi:10.1016/j.jqsrt.2018.07.012

Marvel analysis of the measured high-resolution rovibrational spectra of H₂³²S

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Author: Chubb, Katy L.1; Naumenko, Olga2; Keely, Stefan3;
Organizations: 1Department of Physics and Astronomy, University College London
2V. E. Zuev Institute of Atmospheric Optics, Siberian Branch Russian Academy of Sciences
3Highams Park School
4Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China
5Department of Physics, University of Oulu
6Université Grenoble Alpes, CNRS, LIPhy
7Institute of Chemistry, Eötvös Loránd University and MTA-ELTE Complex Chemical Systems Research Group
Format: article
Version: published version
Access: open
Online Access: PDF Full Text (PDF, 1 MB)
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Language: English
Published: Elsevier, 2018
Publish Date: 2018-10-12


44 325 measured and assigned transitions of H₂³²S, the parent isotopologue of the hydrogen sulfide molecule, are collated from 33 publications into a single database and reviewed critically. Based on this information, rotation-vibration energy levels are determined for the ground electronic state using the Measured Active Rotational-Vibrational Energy Levels (Marvel) technique. The ortho and para principal components of the measured spectroscopic network of H₂³²S are considered separately. The verified set of 25 293 ortho-- and 18 778 para- H₂³²S transitions determine 3969 ortho and 3467 para energy levels. The Marvel results are compared with alternative data compilations, including a theoretical variational linelist.

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Series: Journal of quantitative spectroscopy & radiative transfer
ISSN: 0022-4073
ISSN-E: 1879-1352
ISSN-L: 0022-4073
Volume: 218
Pages: 178 - 186
DOI: 10.1016/j.jqsrt.2018.07.012
Type of Publication: A1 Journal article – refereed
Field of Science: 114 Physical sciences
Funding: This work was supported by STFC Project ST/J002925, the RSF (grant 17-12-01204), the ERC under Advanced Investigator Project 267219, NKFIH (grant K119658), and the COST action MOLIM: Molecules in Motion (CM1405).
Copyright information: © 2018 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license. (