University of Oulu

Henri Järvinen, Mari Honkanen, Madan Patnamsetty, Sanna Järn, Esa Heinonen, Hua Jiang, Pasi Peura, Press hardening of zinc-coated boron steels: Role of steel composition in the development of phase structures within coating and interface regions, Surface and Coatings Technology, Volume 352, 2018, Pages 378-391, ISSN 0257-8972,

Press hardening of zinc-coated boron steels : role of steel composition in the development of phase structures within coating and interface regions

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Author: Järvinen, Henri1; Honkanen, Mari1; Patnamsetty, Madan1;
Organizations: 1Laboratory of Materials Science, Tampere University of Technology, P.O. Box 589, FI-33101 Tampere, Finland
2SSAB Europe Oy, Harvialantie 420, FI-13300 Hämeenlinna, Finland
3Center of Microscopy and Nanotechnology, University of Oulu, P.O. Box 7150, FI-90014 Oulu, Finland
4Nanomicroscopy Center, Aalto University, P.O. Box 15100, FI-00076, Aalto, Finland
Format: article
Version: accepted version
Access: embargoed
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Language: English
Published: Elsevier, 2018
Publish Date: 2020-08-14


Zn and ZnFe coated 22MnB5 and 34MnB5 steels were subjected to the direct press hardening process in order to investigate the influence of steel composition on the resulting phase structures. Microstructures were characterized using advanced methods of microscopy. In addition, X-ray diffraction, glow discharge optical emission spectroscopy and thermodynamic calculations with Thermo-Calc® were carried out to support the analysis. The results indicate that the steel composition has a clear effect on the phase development within coating and interface regions. Whereas the behavior of the 22MnB5 was comparable to earlier investigations, a clearly non-conventional behavior of the 34MnB5 was observed: the formation of martensitic micro constituents, designated here as α′-Fe(Zn), were identified after die-quenching. The regions of the α′-Fe(Zn) formed mainly in vicinity of steel/coating interface and were emerged into the steel by sharing martensitic morphology with the base steel. The thermodynamic calculations suggest that carbon is effective in stabilizing the γ-Fe(Zn) phase, which enables the formation of the α′-Fe(Zn) in fast cooling. Therefore, the higher initial C content of the 34MnB5 may result in the kinetic stabilization of the γ-Fe(Zn) as the inter-diffusion between Zn and Fe occurs during annealing. Simultaneously occurring carbon partitioning from α-Fe(Zn) to γ-Fe(Zn) could explain a clearly increased C content of the coating/steel interface as well as higher Zn contents in the α′-Fe(Zn) phase compared to 22MnB5. Actually, the present study shows that the same phenomenon occurs also in 22MnB5 steels, but in a much smaller scale. In Zn and ZnFe coated 34MnB5, the thickness of the α′-Fe(Zn) layer was increased with longer annealing times and at higher temperatures. The morphology of the α′-Fe(Zn) layer resembled plate-like martensite and can be assumed to be brittle. Regarding this, the formation of α′-Fe(Zn) interface layer needs to be taken into account in press hardening of 34MnB5 steels.

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Series: Surface & coatings technology
ISSN: 0257-8972
ISSN-E: 1879-3347
ISSN-L: 0257-8972
Volume: 352
Pages: 378 - 391
DOI: 10.1016/j.surfcoat.2018.08.040
Type of Publication: A1 Journal article – refereed
Field of Science: 216 Materials engineering
Funding: This study was financially supported by the Finnish Funding Agency for Technology and Innovation (Tekes) in the Breakthrough Steels and Applications Program of the Finnish Metals and Engineering Competence Cluster (FIMECC Ltd), which is gratefully acknowledged. The author wants to thank the Tampere University of Technology (TUT's Graduate School), Emil Aaltonen Foundation, and Finnish Foundation for Technology Promotion for financial support.
Copyright information: © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license