Sintering behavior and characteristics study of BaTiO₃ with 50 wt% of B₂O₃-Bi₂O₃-SiO₂-ZnO glass |
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Author: | Chen, Mei-Yu1; Juuti, Jari1; Hsi, Chi-Shiung2; |
Organizations: |
1Microelectronics Research Unit, Faculty of Information Technology and Electrical Engineering, P.O. Box 4500, FI-90014, University of Oulu, Finland 2Department of Material Science and Engineering, National United University, Miao-Li, 36003, Taiwan |
Format: | article |
Version: | accepted version |
Access: | open |
Online Access: | PDF Full Text (PDF, 1.3 MB) |
Persistent link: | http://urn.fi/urn:nbn:fi-fe201903269976 |
Language: | English |
Published: |
Elsevier,
2017
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Publish Date: | 2019-03-26 |
Description: |
AbstractThe thermal analysis of B₂O₃-Bi₂O₃-SiO₂-ZnO (BBSZ) glass with different particle sizes and LiF addition was researched to study its temperature behavior. Next the composites with 50 wt% BaTiO₃–50 wt% BBSZ glass were prepared for shrinkage, microstructures and dielectric properties investigations. The differently treated BBSZ glass showed that the smaller glass particles clearly decreased its softening and crystallization temperatures. LiF addition had the same but much weaker effect. The composites showed two-stage shrinkage related to the softening of the glass and new phase generation of Bi₂₄Si₂O₄₀ at 385–450 °C, and Bi₄BaTi₄O₁₅ over 680 °C. The microstructures of the composites sintered at 720 °C showed Bi₄BaTi₄O₁₅, BaTiO₃ and Bi₂₄Si₂O₄₀ with residual ZnO phase. LiF addition increased the amount of Bi₄BaTi₄O₁₅, thus increasing the loss value. However the particle size of the glass did not effect to the dielectric properties of the composites showing permittivity of 248–256 and loss of 0.013 at 100 kHz. see all
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Series: |
Journal of the European Ceramic Society |
ISSN: | 0955-2219 |
ISSN-E: | 1873-619X |
ISSN-L: | 0955-2219 |
Volume: | 37 |
Issue: | 4 |
Pages: | 1495 - 1500 |
DOI: | 10.1016/j.jeurceramsoc.2016.10.036 |
OADOI: | https://oadoi.org/10.1016/j.jeurceramsoc.2016.10.036 |
Type of Publication: |
A1 Journal article – refereed |
Field of Science: |
216 Materials engineering 213 Electronic, automation and communications engineering, electronics |
Subjects: | |
Funding: |
The work is supported by the European Research Council (ERC) under the European Union’s Seventh Framework Programme (FP7/2007-2013)/ERC Grant agreement (No. 291132). Author JJ acknowledges the funding of the Academy of Finland (project numbers 267573 and 273663). |
EU Grant Number: |
(291132) ULTIMATE CERAMICS - Printed Electroceramics with Ultimate Compositions |
Academy of Finland Grant Number: |
267573 273663 |
Detailed Information: |
267573 (Academy of Finland Funding decision) 273663 (Academy of Finland Funding decision) |
Copyright information: |
© 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ |
https://creativecommons.org/licenses/by-nc-nd/4.0/ |