Tyunina, M., Pacherova, O., Peräntie, J., Savinov, M., Jelinek, M., Jantunen, H., & Dejneka, A. (2019). Perovskite ferroelectric tuned by thermal strain. Scientific Reports, 9(1). https://doi.org/10.1038/s41598-019-40260-y
Perovskite ferroelectric tuned by thermal strain
|Author:||Tyunina, Marina1,2; Pacherova, Oliva2; Peräntie, Jani1;|
1Microelectronics Research Unit, University of Oulu, P.O. Box 4500, FI-90014, Oulu, Finland
2Institute of Physics of the Czech Academy of Sciences, Na Slovance 2, 18221, Prague, Czech Republic
|Online Access:||PDF Full Text (PDF, 1.7 MB)|
|Persistent link:|| http://urn.fi/urn:nbn:fi-fe2019090526956
|Publish Date:|| 2019-09-05
Modern environmental and sustainability issues as well as the growing demand for applications in the life sciences and medicine put special requirements to the chemical composition of many functional materials. To achieve desired performance within these requirements, innovative approaches are needed. In this work, we experimentally demonstrate that thermal strain can effectively tune the crystal structure and versatile properties of relatively thick films of environmentally friendly, biocompatible, and low-cost perovskite ferroelectric barium titanate. The strain arises during post-deposition cooling due to a mismatch between the thermal expansion coefficients of the films and the substrate materials. The strain-induced in-plane polarization enables excellent performance of bottom-to-top barium titanate capacitors akin to that of exemplary lead-containing relaxor ferroelectrics. Our work shows that controlling thermal strain can help tailor response functions in a straightforward manner.
|Type of Publication:||
A1 Journal article – refereed
|Field of Science:||
216 Materials engineering
The authors acknowledge support from the European Structural and Investment Funds and the Ministry of Education, Youth and Sports of the Czech Republic through Programme “Research, Development and Education” (Project No. SOLID21 - CZ.02.1.01/0.0/0.0/16_019/0000760), the Czech Science Foundation (Grant No. 1909671S), the Academy of Finland (Grant No. 298409), and the European Research Council (Advanced Grant No. 291132).
|EU Grant Number:||
(291132) ULTIMATE CERAMICS - Printed Electroceramics with Ultimate Compositions
|Academy of Finland Grant Number:||
298409 (Academy of Finland Funding decision)
© The Author(s) 2019. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.