University of Oulu

Toni Varila, Henrik Romar, Tero Luukkonen, Tuomo Hilli, Ulla Lassi, Characterization of lignin enforced tannin/furanic foams, Heliyon, Volume 6, Issue 1, 2020, e03228, ISSN 2405-8440, https://doi.org/10.1016/j.heliyon.2020.e03228

Characterization of lignin enforced tannin/furanic foams

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Author: Varila, Toni1; Romar, Henrik2; Luukkonen, Tero3;
Organizations: 1University of Jyvaskyla, Kokkola University Consortium Chydenius, Applied Chemistry, P.O. Box 567, FI-67101, Kokkola, Finland
2University of Oulu, Research Unit of Sustainable Chemistry, P.O. Box 8000, FI-90014, University of Oulu, Finland
3University of Oulu, Fibre and Particle Engineering Research Unit, P.O. Box 8000, FI-90014, University of Oulu, Finland
4Fifth Innovation Oy, P.O. Väinölänkatu 2685, FI-33500, Tampere, Finland
Format: article
Version: published version
Access: open
Online Access: PDF Full Text (PDF, 0.7 MB)
Persistent link: http://urn.fi/urn:nbn:fi-fe202002044396
Language: English
Published: Elsevier, 2020
Publish Date: 2020-02-04
Description:

Abstract

Worldwide, tons of lignin is produced annually in pulping plants and it is mainly considered as a waste material. Usually lignin is burned to produce energy for the pulping reactors. The production of value-added materials from renewable materials like lignin, has proved to be challenging. In this study, the effects of addition of three different types of lignin in the production of tannin/furanic foams is investigated. The foams were matured, first at 373 K and finally carbonized at 1073 K and the properties of them including mechanical strength, specific surface area and pore development are investigated before and after thermal treatment. According to the results, higher mechanical strength is obtained if samples are carbonized at 1073K compared to matured ones at 373K. Up to 10 times stronger materials are achieved this way, which makes them promising as insulating or constructive materials. With physical activation, it is possible to obtain specific surface areas and pore volumes close to 1200 m2/g and 0,55 cm3/g respectively. Mainly micropores are developed during the steam activation which makes these foams more suitable and selective to be used as catalyst support materials in the catalytic conversion of small molecules or in adsorption or gas storage application.

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Series: Heliyon
ISSN: 2405-8440
ISSN-E: 2405-8440
ISSN-L: 2405-8440
Volume: 5
Issue: 1
Article number: e03228
DOI: 10.1016/j.heliyon.2020.e03228
OADOI: https://oadoi.org/10.1016/j.heliyon.2020.e03228
Type of Publication: A1 Journal article – refereed
Field of Science: 116 Chemical sciences
Subjects:
Funding: Toni Varila was supported by the Green bioraff solutions project (EU/Interreg/Botnia-Atlantica, 20201508).
Copyright information: © 2020 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).Heliyon 6 (2020) e03228
  https://creativecommons.org/licenses/by-nc-nd/4.0/