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Kaitao Zhang, Minggui Shen, He Liu, Shibin Shang, Dan Wang, Henrikki Liimatainen, Facile synthesis of palladium and gold nanoparticles by using dialdehyde nanocellulose as template and reducing agent, Carbohydrate Polymers, Volume 186, 2018, Pages 132-139, ISSN 0144-8617, https://doi.org/10.1016/j.carbpol.2018.01.048

Facile synthesis of palladium and gold nanoparticles by using dialdehyde nanocellulose as template and reducing agent

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Author: Zhang, Kaitao1,2; Shen, Minggui2,3; Liu, He2,3;
Organizations: 1Fiber and Particle Engineering Research Unit, University of Oulu, P.O. Box 4300, FI-90014, Finland
2Institute of Chemical Industry of Forest Products, CAF, Key and Open Lab of Forest Chemical Engineering, SFA, Nanjing 210042, China
3Research Institute of Forestry New Technology, CAF, Beijing 100091, China
Format: article
Version: accepted version
Access: open
Online Access: PDF Full Text (PDF, 1 MB)
Persistent link: http://urn.fi/urn:nbn:fi-fe2020102687824
Language: English
Published: Elsevier, 2018
Publish Date: 2020-10-26
Description:

Abstract

Cellulose nanofibrils (CNFs) were firstly prepared by 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) oxidation and further oxidized to 2,3-dialdehyde nanocelluloses (DANCs) by periodate oxidation. Furthermore, by using DANCs as reducing as well as stabilizing agent, palladium (Pd) and gold (Au) nanoparticles (NPs) supported on nanocellulose (PdNPs@NC and AuNPs@NC) were synthesized, respectively. The reduction of Pd or Au ions to its metallic form by DANCs was confirmed by UV–vis spectra, XRD, and XPS. TEM results showed that Pd and Au NPs were homogenously deposited onto cellulose nanofibrils, respectively. The catalytic performance of PdNPs@NC was further investigated by Suzuki coupling reaction. The product yield of the Suzuki coupling reaction between aryl bromides and phenyl boronic acid was more than 90% after 1 h with 0.1 mol% PdNPs@NC catalyst, which demonstrated that the synthesized PdNPs@NC nanohybrid could be successfully applied in Suzuki coupling reaction with an efficient catalytic activity.

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Series: Carbohydrate polymers
ISSN: 0144-8617
ISSN-E: 1879-1344
ISSN-L: 0144-8617
Volume: 186
Pages: 132 - 139
DOI: 10.1016/j.carbpol.2018.01.048
OADOI: https://oadoi.org/10.1016/j.carbpol.2018.01.048
Type of Publication: A1 Journal article – refereed
Field of Science: 221 Nanotechnology
216 Materials engineering
215 Chemical engineering
Subjects:
Aldehyde
Catalysis
Cellulose nanofibrils
Gold
Nanoparticles
Palladium
Article
Funding: The authors would like to thank the National “Twelfth Five-Year” Plan for Science & Technology Support of China (2015BAD14B06) and Academy of Finland for funding (Project No. 307086).
Academy of Finland Grant Number: 307086
Detailed Information: 307086 (Academy of Finland Funding decision)
Copyright information: © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/.
  https://creativecommons.org/licenses/by-nc-nd/4.0/