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Vielma, T., Uusi-Kyyny, P., Salminen, J., Alopaeus, V., & Lassi, U. (2020). Volumetric Properties of Aqueous Solutions of Zinc Sulfate at Temperatures from 298.15 to 393.15 K and Pressures up to 10 MPa. Journal of Chemical & Engineering Data, 66(1), 45–57. https://doi.org/10.1021/acs.jced.0c00767

Volumetric properties of aqueous solutions of zinc sulfate at temperatures from 298.15 to 393.15 K and pressures up to 10 MPa

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Author: Vielma, Tuomas1; Uusi-Kyyny, Petri2; Salminen, Justin3;
Organizations: 1Research Unit of Sustainable Chemistry, University of Oulu, FI-90014 Oulu, Finland
2Department of Chemical and Metallurgical Engineering, School of Chemical Engineering, Aalto University, FI-00076 Aalto, Finland
3Boliden Kokkola Oy, FI-67900 Kokkola, Finland
Format: article
Version: accepted version
Access: open
Online Access: PDF Full Text (PDF, 1.8 MB)
Persistent link: http://urn.fi/urn:nbn:fi-fe2020112693303
Language: English
Published: American Chemical Society, 2020
Publish Date: 2021-11-18
Description:

Abstract

Densities of aqueous solutions of zinc sulfate at molalities ranging from 0.1 to 3.0 mol·kg⁻¹ were measured with a commercial vibrating tube densimeter at temperatures from 298.15 to 393.15 K and at pressures up to 10 MPa. Comparison between the present values and literature data showed a good agreement in general; however, a direct comparison could be made only at 298.15 K. Isothermal compressibilities derived from the density measurements as a function of pressure also compared favorably with literature values based on speed-of-sound measurements.

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Series: Journal of chemical & engineering data
ISSN: 0021-9568
ISSN-E: 1520-5134
ISSN-L: 0021-9568
Volume: 66
Issue: 1
Pages: 45 - 57
DOI: 10.1021/acs.jced.0c00767
OADOI: https://oadoi.org/10.1021/acs.jced.0c00767
Type of Publication: A1 Journal article – refereed
Field of Science: 116 Chemical sciences
Subjects:
Anions
Calibration
Solution chemistry
Vacuum
Zinc
Article
Funding: Saostus (A301153, EU/European Regional Development Fund) and AdChem (Tekes, 1792/31/2016) projects, and Walther Ahlström Foundation are acknowledged for research funding.
Copyright information: This document is the Accepted Manuscript version of a Published Work that appeared in final form in J. Chem. Eng. Data, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.jced.0c00767.