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Chem. Commun., 2021,57, 8264-8267, http://dx.doi.org/10.1039/D1CC02579A Direct enantiomeric discrimination through antisymmetric hyperfine coupling |
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| Author: | Garbacz, Piotr1; Vaara, Juha2 |
| Organizations: |
1Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland 2NMR Research Unit, University of Oulu, P.O. Box 3000, FI-90014 Oulu, Finland |
| Format: | article |
| Version: | published version |
| Access: | open |
| Online Access: | PDF Full Text (PDF, 2.7 MB) |
| Persistent link: | http://urn.fi/urn:nbn:fi-fe2021083044589 |
| Language: | English |
| Published: |
Royal Society of Chemistry,
2021
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| Publish Date: | 2021-08-30 |
| Description: |
AbstractChiral open-shell molecules possessing permanent electric dipole moments have an EPR signal at the difference frequency of the electron and nuclear resonances, allowing direct enantiomeric discrimination by signal phase. The effect depends on the vector antisymmetry of the hyperfine coupling. Quantum chemistry suggests chiral bisfluorene methyl radical derivatives as promising for experiments. see all
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| Series: |
Chemical communications |
| ISSN: | 1359-7345 |
| ISSN-E: | 1364-548X |
| ISSN-L: | 1359-7345 |
| Volume: | 57 |
| Issue: | 67 |
| Pages: | 8264 - 8267 |
| DOI: | 10.1039/d1cc02579a |
| OADOI: | https://oadoi.org/10.1039/d1cc02579a |
| Type of Publication: |
A1 Journal article – refereed |
| Field of Science: |
114 Physical sciences 116 Chemical sciences |
| Subjects: | |
| Copyright information: |
This journal is © The Royal Society of Chemistry 2021. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. |
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https://creativecommons.org/licenses/by-nc/3.0/ |