Abstract

Determining non-metallic inclusions (NMIs) are essential to engineer ultra-high-strength steel as they play decisive role on performance and critical to probe via conventional techniques. Herein, advanced Synchrotron X-ray absorption coupled with photoemission electron microscopy and first-principles calculations are employed to provide the structure, local bonding structure and electronic properties of several NMI model systems and their interaction mechanism within and the steel matrix. B K-, N K-, Ca L_2,3- and Ti L_2,3-edge spectra show that the additional B prefers to result in h-BN exhibiting strong interaction with Ca²⁺. Such Ca²⁺-based phases also stabilize through TiN, revealing the irregular coordination of Ca²⁺. Observed intriguing no interaction between TiN and BN is further supported with the first-principles calculations, wherein unfavorable combination of TiN and h-BN and stabilization of bigger sized Ca²⁺-based inclusions have been found. These observations can help to optimize the interaction mechanism among various inclusions as well as steel matrix.