University of Oulu

Khalili, R., Kantola, A. M., Komulainen, S., Selent, A., Selent, M., Vaara, J., Larsson, A.-C., Lantto, P., & Telkki, V.-V. (2022). 129Xe NMR analysis of pore structures and adsorption phenomena in rare-earth element phosphates. Microporous and Mesoporous Materials, 344, 112209. https://doi.org/10.1016/j.micromeso.2022.112209

¹²⁹Xe NMR analysis of pore structures and adsorption phenomena in rare-earth element phosphates

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Author: Khalili, Roya1; Kantola, Anu M.1; Komulainen, Sanna1;
Organizations: 1NMR Research Unit, University of Oulu, P.O.Box 3000, FIN-90014, Finland
2Centre for Material Analysis, University of Oulu, P.O.Box 3000, FIN-90014, Finland
3Chemistry of Interfaces, Luleå University of Technology, SE-97187 Luleå, Sweden
Format: article
Version: published version
Access: open
Online Access: PDF Full Text (PDF, 2.3 MB)
Persistent link: http://urn.fi/urn:nbn:fi-fe2022102563242
Language: English
Published: Elsevier, 2022
Publish Date: 2022-10-25
Description:

Abstract

Rare-earth elements (REEs) are indispensable in various applications ranging from catalysis to batteries and they are commonly found from phosphate minerals. Xenon is an excellent exogenous NMR probe for materials because it is inert and its ¹²⁹Xe chemical shift is very sensitive to its local physical or chemical environment. Here, we exploit, for the first time, ¹²⁹Xe NMR for the characterization of porous structures and adsorption properties of REE phosphates (REEPO₄). We study four different REEPO₄ samples (REE = La, Lu, Sm and Yb), including both light (La and Sm) and heavy (Lu and Yb) as well as diamagnetic (La and Lu) and paramagnetic (Sm and Yb) REEs. ¹²⁹Xe resonances are very sensitive to the porous structures and moisture content of the REEPO₄ samples. In the samples treated at a lower temperature (80 °C), free water hinders the access of hydrophobic xenon into small mesopores, but the treatment at a higher temperature (200 °C) removes the free water and allows xenon to explore the mesopores. Based on a standard two-site exchange model analysis of the variable-temperature ¹²⁹Xe chemical shifts, as well as its proposed, novel modification for paramagnetic materials, the average mesopore sizes were determined. The size was the largest (79 nm) for the La sample with mixed monazite (70%) and rhabdophane (30%) phases and the smallest (6 nm) for the Yb sample with pure xenotime phase. The mesopore sizes of the Lu and Yb samples (12 and 6 nm) differed by a factor of two regardless of their similar xenotime phase. The ¹²⁹Xe NMR analysis revealed that the heats of adsorption of the samples are similar, varying between 8.7 and 10.1 kJ/mol. For diamagnetic samples, computational modelling confirmed the order of magnitude of the chemical shifts of Xe adsorbed on surfaces and therefore the validity of the two-site exchange model analysis. Overall, ¹²⁹Xe NMR provides exceptionally versatile information about the pore structures and adsorption properties of REEPO₄ materials, which may be very useful for developing the extraction processes and applications of REEs.

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Series: Microporous and mesoporous materials
ISSN: 1387-1811
ISSN-E: 1873-3093
ISSN-L: 1387-1811
Volume: 344
Article number: 112209
DOI: 10.1016/j.micromeso.2022.112209
OADOI: https://oadoi.org/10.1016/j.micromeso.2022.112209
Type of Publication: A1 Journal article – refereed
Field of Science: 114 Physical sciences
116 Chemical sciences
Subjects:
Funding: The authors acknowledge financial support from the European Research Council (ERC) under Horizon 2020 (H2020/2018–2022/ERC grant agreement no. 772110), Academy of Finland (grant nos. 331008 and 340099), Formas project 2018–00630, and Kvantum institute (University of Oulu). Computational resources due to CSC (Espoo, Finland) and the Finnish Grid and Cloud Infrastructure project (persistent identifier urn:nbn:fi:research-infras-2016072533), were used. Part of the work was carried out with the support of the Center for Material Analysis, University of Oulu, Finland.
Academy of Finland Grant Number: 331008
340099
Detailed Information: 331008 (Academy of Finland Funding decision)
340099 (Academy of Finland Funding decision)
Copyright information: © 2022 The Authors. Published by Elsevier Inc. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
  https://creativecommons.org/licenses/by/4.0/