University of Oulu

Wei, J., Ma, J., Wang, W. et al. Study of the Effect of F-Doping on Lithium Electrochemical Behavior in MnWO4 Anode Nanomaterials. J Inorg Organomet Polym 31, 3175–3182 (2021).

Study of the effect of F-doping on lithium electrochemical behavior in MnWO₄ anode nanomaterials

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Author: Wei, Jianyu1; Ma, Jinxiu2; Wang, Wei3;
Organizations: 1China Tobacco Guangxi Industrial Co., Ltd, Nanning, Guangxi, 530001, People’s Republic of China
2Key Lab of Environment Friendly Chemistry and Application in Ministry of Education, College of Chemistry, Institution Xiangtan University, Xiangtan, 411105, People’s Republic of China
3Key Laboratory of Inorganic Nanomaterials of Hebei Province, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, 050016, People’s Republic of China
4Nano and Molecular Systems Research Unit, University of Oulu, P. O. Box 3000, 90014, Oulu, Finland
5School of Mechanical Engineering, Guizhou University, Guiyang, 550025, Guizhou, China
Format: article
Version: accepted version
Access: open
Online Access: PDF Full Text (PDF, 0.8 MB)
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Language: English
Published: Springer Nature, 2021
Publish Date: 2023-01-13


MnWO₄ nanorods with different contents of F-doping were synthesized by a facile approach. The morphological studies further confirmed formation of MnWO₄ nanorod structure with dimensional size and length of 50 and 100 nm, respectively. The differences of Li-storage performance that caused by F-doping contents in MnWO₄ nanomaterials were systematically investigated. The results show by tuning the F-doping contents in the MnWO₄ nanorods, both the reversible capacity and the cycling stability of nano-MnWO₄ electrode attain remarkable improvement. Furthermore when the content of F-doping is 0.05 mol%, the reversible capacity for lithium storage in nano-MnWO₄ is at its maximum. What makes that all the more remarkable is that the 0.05 mol% F-doped nano-MnWO₄ shows a long cycle life. Even cycled under a low current density (200 mA h g⁻¹), the capacity retention still can keep more than 85% after 150 cycles, which are much superior to the report ones. These results provide insight into the effective method which can easily be applied to improve the electrochemical performances of the advanced electrode materials for Li ion batteries.

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Series: Journal of inorganic and organometallic polymers and materials
ISSN: 1574-1443
ISSN-E: 1574-1451
ISSN-L: 1574-1443
Volume: 31
Issue: 7
Pages: 3175 - 3182
DOI: 10.1007/s10904-021-01987-2
Type of Publication: A1 Journal article – refereed
Field of Science: 216 Materials engineering
Funding: The authors acknowledge with thanks the financial support of Hunan 2011 Collaborative Innovation Center of Chemical Engineering and Technology with Environmental Benignity and Effective Resource Utilization and the National Natural Science Foundation of China (51965009), the Natural Science Fundation of Hebei province (B2017205149), and the Hebei Provincial University Young Talent Program (BJ2017042) and Science and Technology Plan Project of Guizhou Province: [2019]5616.
Copyright information: © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021. This version of the article has been accepted for publication, after peer review (when applicable) and is subject to Springer Nature’s AM terms of use, but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: