Usage of phosphoric acid plant’s circulate pond waters in struvite precipitation : effect of conditions |
|
Author: | Tuomikoski, Sari1; Sauvola, Emilia1; Riponiemi, Marko2; |
Organizations: |
1Research Unit of Sustainable Chemistry, University of Oulu, Oulu, Finland 2Yara, Siilinjärvi, Finland |
Format: | article |
Version: | accepted version |
Access: | embargoed |
Persistent link: | http://urn.fi/urn:nbn:fi-fe202301306551 |
Language: | English |
Published: |
John Wiley & Sons,
2023
|
Publish Date: | 2024-01-19 |
Description: |
AbstractStruvite is a suitable fertilizer, and electrochemical precipitation of nutrients from industrial waters provides one answer to the circular economy. Molar ratio between ammonium and phosphate is crucial: Water suitable for the precipitation includes more or at least the same amount ammonium than phosphate. That kind of water typically does not exist in industry. Therefore, ammonium-rich industrial water was mixed with phosphorus-rich water to obtain a suitable molar ratio for struvite precipitation. Parameters were studied to determine their effect on removal-% and struvite yield. 100% struvite yield was obtained under several conditions even without pH control with pH 7–9. The highest phosphate removal (99.7%) was occurred with the molar ratio 1.7:2:1 for Mg:NH₄:PO₄ (pH 9.0). Waters dilution prevents magnesium anode corrosion. Formed struvite has potential as recycled fertilizer due to low bioavailability of metals and high leachability of nutrients studied by four-stage sequential leaching. see all
|
Series: |
Water and environment journal |
ISSN: | 1747-6585 |
ISSN-E: | 1747-6593 |
ISSN-L: | 1747-6585 |
DOI: | 10.1111/wej.12848 |
OADOI: | https://oadoi.org/10.1111/wej.12848 |
Type of Publication: |
A1 Journal article – refereed |
Field of Science: |
116 Chemical sciences |
Subjects: | |
Funding: |
This work was conducted under the auspices of the Waterpro (ERDF project number: A74635, funded by the European Union, European Regional Development Fund, Leverage from the EU Central and Ostrobothnia Regional Council) and the project “Reaching congenial region through valorisation of municipal and industrial wastewaters and sludge” (Waste Recycling, KA4020) funded by the Karelia CBC Program. |
Copyright information: |
© 2023 CIWEM. This is the peer reviewed version of the following article: Tuomikoski, S., Sauvola, E., Riponiemi, M., Lassi, U. & Pesonen, J. (2023) Usage of phosphoric acid plant's circulate pond waters in struvite precipitation—Effect of conditions. Water and Environment Journal, 1–9, which has been published in final form at https://doi.org/10.1111/wej.12848. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |