A facile synthesis of K₃PMo₁₂O₄₀/WO₃ crystals for effective sonocatalytic performance
|Author:||Li, Linjing1; Li, Feng1,2; Li, Taohai1,2;|
1College of Chemistry, Key Lab of Environment Friendly Chemistry and Application in Ministry of Education, Xiangtan University, Xiangtan, China
2Nano and Molecular Materials Research Unit, Faculty of Science, University of Oulu, P.O. Box 3000, Oulu, Finland
|Online Access:||PDF Full Text (PDF, 1.4 MB)|
|Persistent link:|| http://urn.fi/urn:nbn:fi-fe2023053150675
Royal Society of Chemistry,
|Publish Date:|| 2023-05-31
Proper treatment of hazardous contaminants in the air, land, and water is crucial to environmental remediation. Sonocatalysis, by using ultrasound and suitable catalysts, has shown its potential in organic pollutant removal. In this work, K₃PMo₁₂O₄₀/WO₃ sonocatalysts were fabricated via a facile solution method at room temperature. Techniques such as powder X-ray diffraction, scanning electron microscopy (SEM), transmission electron microscopy, and X-ray photoelectron spectroscopy were used to characterize the structure and morphology of the products. By using the K₃PMo₁₂O₄₀/WO₃ sonocatalyst, an ultrasound-assisted advanced oxidation process has been developed for the catalytic degradation of methyl orange and acid red 88. Almost all dyes were degraded within 120 min of ultrasound baths, proving that the K₃PMo₁₂O₄₀/WO₃ sonocatalyst has the advantage of speeding up the decomposition of contaminants. The impacts of key parameters, including catalyst dosage, dye concentration, dye pH, and ultrasonic power were evaluated to understand and reach optimized conditions in sonocatalysis. The remarkable performance of K₃PMo₁₂O₄₀/WO₃ in the sonocatalytic degradation of pollutants provides a new strategy for the application of K₃PMo₁₂O₄₀ in sonocatalysis.
|Pages:||15981 - 15992|
|Type of Publication:||
A1 Journal article – refereed
|Field of Science:||
216 Materials engineering
The authors acknowledge with thanks the financial support of the National Natural Science Foundation of China (21601149). W. Cao acknowledges funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement no. 101002219).
|EU Grant Number:||
(101002219) CATCH - Cross-dimensional Activation of Two-Dimensional Semiconductors for Photocatalytic Heterojunctions
© 2022 The Author(s). Published by the Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.