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Ruthenium-assisted tellurium abstraction in bis(thiophen-2-yl) ditelluride |
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| Author: | Taimisto, Marjaana1; Poropudas, Merja J.1; Rautiainen, J. Mikko2; |
| Organizations: |
1Laboratory of Inorganic Chemistry, Environmental and Chemical Engineering, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland 2Department of Chemistry, Nanoscience Center, University of Jyväskylä, P.O. Box 35, 40014 Jyväskylä, Finland |
| Format: | article |
| Version: | published version |
| Access: | open |
| Online Access: | PDF Full Text (PDF, 4.9 MB) |
| Persistent link: | http://urn.fi/urn:nbn:fi-fe20231003138477 |
| Language: | English |
| Published: |
John Wiley & Sons,
2023
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| Publish Date: | 2023-10-03 |
| Description: |
AbstractThe reaction of [RuCl₂(CO)₃]₂ and Te₂Tpn₂ (Tpn=thiophen-2-yl, C₄H₃S) in the absence of light resulted in the formation of cct-[RuCl₂(CO)₂(TeTpn₂)₂] (1) [cis(Cl)-cis(CO)-trans(TeTpn₂)] and TeTpn₂ (2) together with the precipitation of tellurium. The complex 1 and the monotelluride 2 were characterized by NMR spectroscopy and single-crystal X-ray diffraction. The decomposition of Te₂Tpn₂ to TeTpn₂ has been monitored by ¹²⁵Te NMR spectroscopy and seemed to be faster than the ligand substitution in [RuCl₂(CO)₃]₂ by TeTpn₂. A catalytic cycle is proposed for the decomposition of Te₂Tpn₂ to TeTpn₂ based on the PBE0-D3/def2-TZVP calculations. see all
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| Series: |
European journal of inorganic chemistry |
| ISSN: | 1434-1948 |
| ISSN-E: | 1099-0682 |
| ISSN-L: | 1434-1948 |
| Volume: | 26 |
| Issue: | 14 |
| Article number: | e202200772 |
| DOI: | 10.1002/ejic.202200772 |
| OADOI: | https://oadoi.org/10.1002/ejic.202200772 |
| Type of Publication: |
A1 Journal article – refereed |
| Field of Science: |
116 Chemical sciences |
| Subjects: | |
| Funding: |
The Alfred Kordelin Foundation (Grant no. 210317) and Tauno Tönning Research Foundation (M. T.), and provision of computational resources by Prof. Heikki Tuononen (University of Jyväskylä) (J. M. R.) are gratefully acknowledged. |
| Copyright information: |
© 2023 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
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https://creativecommons.org/licenses/by/4.0/ |