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Inversion model for extracting chemically resolved depth profiles across liquid interfaces of various configurations from XPS data : PROPHESY |
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| Author: | Ozon, Matthew1; Tumashevich, Konstantin1; Lin, Jack J.1; |
| Organizations: |
1Center for Atmospheric Research, University of Oulu, PO Box 4500, Finland |
| Format: | article |
| Version: | published version |
| Access: | open |
| Online Access: | PDF Full Text (PDF, 1.4 MB) |
| Persistent link: | http://urn.fi/urn:nbn:fi-fe20231013140041 |
| Language: | English |
| Published: |
International Union of Crystallography,
2023
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| Publish Date: | 2023-10-13 |
| Description: |
AbstractPROPHESY, a technique for the reconstruction of surface-depth profiles from X-ray photoelectron spectroscopy data, is introduced. The inversion methodology is based on a Bayesian framework and primal-dual convex optimization. The acquisition model is developed for several geometries representing different sample types: plane (bulk sample), cylinder (liquid microjet) and sphere (droplet). The methodology is tested and characterized with respect to simulated data as a proof of concept. Possible limitations of the method due to uncertainty in the attenuation length of the photo-emitted electron are illustrated. see all
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| Series: |
Journal of synchrotron radiation |
| ISSN: | 0909-0495 |
| ISSN-E: | 1600-5775 |
| ISSN-L: | 0909-0495 |
| Volume: | 30 |
| Issue: | 5 |
| Pages: | 941 - 961 |
| DOI: | 10.1107/S1600577523006124 |
| OADOI: | https://oadoi.org/10.1107/S1600577523006124 |
| Type of Publication: |
A1 Journal article – refereed |
| Field of Science: |
115 Astronomy and space science |
| Subjects: | |
| Funding: |
The following funding is acknowledged: H2020 European Research Council (grant No. 717022); Academy of Finland (grant No. 308238; grant No. 314175; grant No. 316743; grant No. 335649; grant No. 331532; grant No. 351476). |
| EU Grant Number: |
(717022) SURFACE - The unexplored world of aerosol surfaces and their impacts. |
| Academy of Finland Grant Number: |
308238 314175 316743 335649 331532 351476 |
| Detailed Information: |
308238 (Academy of Finland Funding decision) 314175 (Academy of Finland Funding decision) 316743 (Academy of Finland Funding decision) 335649 (Academy of Finland Funding decision) 331532 (Academy of Finland Funding decision) 351476 (Academy of Finland Funding decision) |
| Copyright information: |
© The Author(s) 2023. Published under a CC BY 4.0 licence. |
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https://creativecommons.org/licenses/by/4.0/ |